Teitl: B(C6F5)3-Catalyzed Direct C3 Alkylation of Indoles and Oxindoles - data
Dyfyniad
Basak S, Alvarez-Montoya A, Winfrey L, et al. (2020). B(C6F5)3-Catalyzed Direct C3 Alkylation of Indoles and Oxindoles - data. Cardiff University. https://doi.org/10.17035/d.2020.0104936560
Hawliau Mynediad: Darperir Data dan drwydded Creative Commons Attribution (CC BY 4.0)
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk
Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2020
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 5298
DOI : 10.17035/d.2020.0104936560
DOI URL: http://doi.org/10.17035/d.2020.0104936560
Related URL: http://blogs.cardiff.ac.uk/themorrillgroup/
The direct C3 alkylation of indoles and oxindoles is a challenging transformation and only a few direct methods exist. Utilizing the underexplored ability of triaryl boranes to mediate the heterolytic cleavage of α-nitrogen C–H bonds in amines, we have developed a catalytic approach for the direct C3 alkylation of a wide range of indoles and oxindoles using amine based alkylating agents. We also employed this borane-catalyzed strategy in an alkylation-ring opening cascade. Analysis of reaction products from this methodology resulted in the following data: 1H, 19F and 13C NMR raw data files IR spectra High resolution mass spectrometry spectra.
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