Teitl: Synthesis and Reactivity of Fluorinated Triaryl Aluminium Complexes - data

Dyfyniad
Ould DMC, Carden JL, Melen RL (2020). Synthesis and Reactivity of Fluorinated Triaryl Aluminium Complexes - data. Cardiff University. http://doi.org/10.17035/d.2020.0114501208


Hawliau Mynediad: Darperir Data dan drwydded Creative Commons Attribution (CC BY 4.0)
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Crewyr y Set Ddata o Brifysgol Caerdydd

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2020
Dyddiad dechrau creu'r data: 01.10.2017
Dyddiad gorffen creu'r data: 19.08.2020
Fformat y data: .pdf, .cif, .jpg
Meddalwedd ofynnol: Mercury, MNova
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit
DOI: 10.17035/d.2020.0114501208

Disgrifiad

The addition of the Grignard 3,4,5-ArFMgBr to aluminium(III) chloride in ether generates the novel triarylalane Al(3,4,5-ArF)3·OEt2. Attempts to synthesize this alane via transmetallation from the parent borane with trimethylaluminium gave a dimeric structure with bridging methyl groups; a product of partial transmetallation. On the other hand, the novel alane Al(2,3,4-ArF)3 was synthesized from the parent borane and trimethylaluminium. Interestingly, the solid-state structure of Al(2,3,4-ArF)3 shows an extended chain structure resulting from neighboring Al···F contacts. Al(3,4,5-ArF)3·OEt2 was then found to be an effective catalyst for the hydroboration of carbonyls, imines and alkynes with pinacolborane. Data include experimental procedures, NMR data, X-ray data and computational data.

Research results based upone these data are published at https://doi.org/10.1021/acs.inorgchem.0c01076



Prosiectau Cysylltiedig

Diweddarwyd y tro diwethaf ar 2020-04-09 am 14:40