Teitl: Synthesis and reactivity of N,N’-1,4-diazabutadiene derived borocations

Dyfyniad
Lawson JR, Wilkins LC, André M, et al. (2017). Synthesis and reactivity of N,N’-1,4-diazabutadiene derived borocations. Cardiff University. https://doi.org/10.17035/d.2017.0011648832

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2017

Dyddiad dechrau creu'r data: 01.03.2016

Dyddiad gorffen creu'r data: 30.09.2016

Fformat y data: .pdf, .cif

Meddalwedd ofynnol: NMR software e.g. MNova
Structure determination/visualisation software e.g. Mercury
Avogadro Software for visualisation of theoretical calculations/

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit

DOI : 10.17035/d.2017.0011648832

DOI URL: http://doi.org/10.17035/d.2017.0011648832

Related URL: http://gow.epsrc.ac.uk/NGBOViewGrant.aspx?GrantRef=EP/N02320X/1

Disgrifiad

A series of borocations have been synthesised from the addition of haloboranes to synthetically accessible N,N′-1,4-diazabutadiene precursors, which are derived from commercially available anilines. The Experimental, X-ray, NMR and computational data are provided. X-ray data are included here which can be visualized using software for X-ray crystal structure determination/visualization which was used to characterise the compounds synthesised. Computation studies by DFT are included.

Results based upon these data are published at http://doi.org/10.1039/c6dt03360a