Title: Expedient Organocatalytic Aza-Morita-Baylis-Hillman Reaction Through Ball-Milling - data

Citation
Browne DL, Williams M (2020). Expedient Organocatalytic Aza-Morita-Baylis-Hillman Reaction Through Ball-Milling - data. Cardiff University. http://doi.org/10.17035/d.2020.0120616585


This data is not currently available because: Intent to publish project results
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Cardiff University Dataset Creators

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2020
Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Software Required: An appropriate NMR processing software is required for raw NMR data files
Estimated total storage size of dataset: Less than 1 gigabyte
DOI: 10.17035/d.2020.0120616585

Description

A ball-milling enabled tertiary amine catalysed aza-Morita-Baylis-Hillman reaction is reported. The reaction process does not require solvent, has significantly shorter reaction times than previous methods, and is reported on a range of imines and acrylate Michael acceptors across more than 25 examples. A 12-fold scaled-up example is also reported as well as experimental comparisons to solution based experiments and neat-stirred reactions included.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.


Research Areas

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Last updated on 2020-12-11 at 14:55