Title: Expedient Organocatalytic Aza-Morita-Baylis-Hillman Reaction Through Ball-Milling - data
Citation
Browne DL, Williams M (2020). Expedient Organocatalytic Aza-Morita-Baylis-Hillman Reaction Through Ball-Milling - data. Cardiff University. https://doi.org/10.17035/d.2020.0120616585
This data is not currently available because: Intent to publish project results
Access Rights: Data is provided under a Creative Commons Attribution (CC BY 4.0) licence
Access Method: https://doi.org/10.17035/d.2020.0120616585 will take you to the repository page for this dataset, where you will be able to download the data or find further access information, as appropriate.
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2020
Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Software Required: An appropriate NMR processing software is required for raw NMR data files
Estimated total storage size of dataset: Less than 1 gigabyte
DOI : 10.17035/d.2020.0120616585
DOI URL: http://doi.org/10.17035/d.2020.0120616585
Related URL: http://www.thebrowneresearchgroup.co.uk/
A ball-milling enabled tertiary amine catalysed aza-Morita-Baylis-Hillman reaction is reported. The reaction process does not require solvent, has significantly shorter reaction times than previous methods, and is reported on a range of imines and acrylate Michael acceptors across more than 25 examples. A 12-fold scaled-up example is also reported as well as experimental comparisons to solution based experiments and neat-stirred reactions included. Analysis of reaction products from this methodology resulted in the following data: 1H, 19F and 13C NMR raw data files IR spectra High-Resolution Mass Spectrography spectra.
Description
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- Enabling Technologies for Synthesis and Catalysis (01/07/2019 - 30/09/2022)
