Teitl: Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)"

Dyfyniad
Ayres JN, Ashford MW, Stockl Y, et al. (2017). Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)". Cardiff University. https://doi.org/10.17035/d.2017.0038300689

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2017

Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd

Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit

Nifer y ffeiliau yn y set ddata: 3063

DOI : 10.17035/d.2017.0038300689

DOI URL: http://doi.org/10.17035/d.2017.0038300689

Related URL: http://blogs.cardiff.ac.uk/themorrillgroup/

Disgrifiad

The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p- methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer reagent and a cyanamide source, accessing a diverse range of ter- tiary cyanamides in excellent isolated yields. This approach exploits the under developed desulfonylative (N-S bond cleavage) reac- tivity pathway of NCTS, which is more commonly employed for electrophilic C- and N-cyanation processes.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.7b01710