Title: Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)"

Citation
Ayres JN, Ashford MW, Stockl Y, et al. (2017). Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)". Cardiff University. https://doi.org/10.17035/d.2017.0038300689

Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2017

Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd

Software Required: An appropriate NMR processing software is required for raw NMR data files

Estimated total storage size of dataset: Less than 1 gigabyte

Number of Files In Dataset: 3063

DOI : 10.17035/d.2017.0038300689

DOI URL: http://doi.org/10.17035/d.2017.0038300689

Related URL: http://blogs.cardiff.ac.uk/themorrillgroup/

Description

The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p- methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer reagent and a cyanamide source, accessing a diverse range of ter- tiary cyanamides in excellent isolated yields. This approach exploits the under developed desulfonylative (N-S bond cleavage) reac- tivity pathway of NCTS, which is more commonly employed for electrophilic C- and N-cyanation processes.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.7b01710