Teitl: Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)"

Dyfyniad
Ayres JN, Ashford MW, Stockl Y, et al. (2017). Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)". Cardiff University. http://doi.org/10.17035/d.2017.0038300689


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Crewyr y Set Ddata o Brifysgol Caerdydd

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2017
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 3063
DOI: 10.17035/d.2017.0038300689

Disgrifiad

The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p- methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer reagent and a cyanamide source, accessing a diverse range of ter- tiary cyanamides in excellent isolated yields. This approach exploits the under developed desulfonylative (N-S bond cleavage) reac- tivity pathway of NCTS, which is more commonly employed for electrophilic C- and N-cyanation processes. 

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.7b01710


Prosiectau Cysylltiedig

Diweddarwyd y tro diwethaf ar 2019-23-07 am 08:52