Title: Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)"

Ayres JN, Ashford MW, Stockl Y, et al. (2017). Data for "Deoxycyanamidation of Alcohols with N-Cyano-N-Phenyl-p-Methylbenzenesulfonamide (NCTS)". Cardiff University. http://doi.org/10.17035/d.2017.0038300689

Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Cardiff University Dataset Creators

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2017
Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Software Required: An appropriate NMR processing software is required for raw NMR data files
Estimated total storage size of dataset: Less than 1 gigabyte
Number of Files In Dataset: 3063
DOI: 10.17035/d.2017.0038300689


The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p- methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer reagent and a cyanamide source, accessing a diverse range of ter- tiary cyanamides in excellent isolated yields. This approach exploits the under developed desulfonylative (N-S bond cleavage) reac- tivity pathway of NCTS, which is more commonly employed for electrophilic C- and N-cyanation processes. 

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.7b01710

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Last updated on 2019-23-07 at 08:52