Title: A quantitative approach to predicting rate constants for aqueous racemization allows pointless stereoselective syntheses to be avoided
Citation
Ballard A, Buurma NJ (2017). A quantitative approach to predicting rate constants for aqueous racemization allows pointless stereoselective syntheses to be avoided. Cardiff University. https://doi.org/10.17035/d.2017.0043106638
Access Rights: Creative Commons Attribution 4.0 International
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2017
Data format: standard Bruker folder structure including FID file
Software Required: To view the data files, software able to read datafiles generated by Bruker NMR instruments is required.
DOI : 10.17035/d.2017.0043106638
DOI URL: http://doi.org/10.17035/d.2017.0043106638
This dataset contains 1H NMR data for arylglycine derivatives in phosphate buffers. This data was recorded as a function of time for samples kept at a constant temperature. Analysis of the decrease of the relative integral for the proton on the stereogenic centre yields the kinetic data reported in https://doi.org/10.1002/ange.201709163.
Description
Research Areas
Related Projects
- Configuration stability (01/10/2007 - 31/03/2011)
