Title: A quantitative approach to predicting rate constants for aqueous racemization allows pointless stereoselective syntheses to be avoided

Citation
Ballard A, Buurma NJ (2017). A quantitative approach to predicting rate constants for aqueous racemization allows pointless stereoselective syntheses to be avoided. Cardiff University. http://doi.org/10.17035/d.2017.0043106638


Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Cardiff University Dataset Creators

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2017
Data format: standard Bruker folder structure including FID file
Software Required: To view the data files, software able to read datafiles generated by Bruker NMR instruments is required.
DOI: 10.17035/d.2017.0043106638

Description

This dataset contains 1H NMR data for arylglycine derivatives in phosphate buffers. This data was recorded as a function of time for samples kept at a constant temperature.

Analysis of the decrease of the relative integral for the proton on the stereogenic centre yields the kinetic data reported in https://doi.org/10.1002/ange.201709163.



Related Projects
Configuration stability (01/10/2007 - 31/03/2011)

Last updated on 2019-07-08 at 14:38