Teitl: Data pertaining to selective synthesis of high purity, crystalline D-glucaric acid

Dyfyniad
Armstrong RD, Kariuki BM, Knight DW, et al. (2017). Data pertaining to selective synthesis of high purity, crystalline D-glucaric acid. Cardiff University. https://doi.org/10.17035/d.2017.0044004605

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2017

Fformat y data: .mwps, .file, .xlsx, .tif, .rtf, .ASC, .xrdml

Meddalwedd ofynnol: TopSpin nmr, PANalytical High Score, Agilent MP Expert, MS Excel,

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit

Nifer y ffeiliau yn y set ddata: 685

DOI : 10.17035/d.2017.0044004605

DOI URL: http://doi.org/10.17035/d.2017.0044004605

Related URL: http://gow.epsrc.ac.uk/NGBOViewGrant.aspx?GrantRef=EP/K014749/1

Disgrifiad

Glucaric acid is a key glucose-derived platform molecule with reported applications in material science and pharmaceutical fields. This article details the first methodology for synthesis of crystalline D-glucaric acid complete with quantitative yields (98.7 %) and spectroscopic analysis, starting from glucaric acid's commercially available forms (Ca/K-glucarate salts).

The data contained herein charts; cation exchange of K-glucarate to yield the free acid glucaric acid - with corresponding time resolved ICP-MS and 1H-NMR analyses. Also included are nmr spectra of the products recovered when recovery of the glucaric acid product was attempted. Finally, nmr spectra, elemental analysis, IR spectra, X-ray diffraction and single-crystal X-ray diffraction datas for the as-sythesised desired product; crystalline D-glucaric acid are presented.

Research results based upon these data are published at http://doi.org/10.1002/ejoc.201701343