Title: Data pertaining to selective synthesis of high purity, crystalline D-glucaric acid


Citation
Armstrong RD, Kariuki BM, Knight DW, et al. (2017). Data pertaining to selective synthesis of high purity, crystalline D-glucaric acid. Cardiff University. http://doi.org/10.17035/d.2017.0044004605



Access Rights: Data can be made freely available subject to attribution

Access Method: Click to email a request for this data to opendata@cardiff.ac.uk


Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2017

Data format: .mwps, .file, .xlsx, .tif, .rtf, .ASC, .xrdml

Software Required: TopSpin nmr, PANalytical High Score, Agilent MP Expert, MS Excel,

Estimated total storage size of dataset: Less than 1 gigabyte

Number of Files In Dataset: 685

DOI : 10.17035/d.2017.0044004605

DOI URL: http://doi.org/10.17035/d.2017.0044004605

Related URL: http://gow.epsrc.ac.uk/NGBOViewGrant.aspx?GrantRef=EP/K014749/1


Description

Glucaric acid is a key glucose-derived platform molecule with reported applications in material science and pharmaceutical fields. This article details the first methodology for synthesis of crystalline D-glucaric acid complete with quantitative yields (98.7 %) and spectroscopic analysis, starting from glucaric acid's commercially available forms (Ca/K-glucarate salts).

The data contained herein charts; cation exchange of K-glucarate to yield the free acid glucaric acid - with corresponding time resolved ICP-MS and 1H-NMR analyses. Also included are nmr spectra of the products recovered when recovery of the glucaric acid product was attempted. Finally, nmr spectra, elemental analysis, IR spectra, X-ray diffraction and single-crystal X-ray diffraction datas for the as-sythesised desired product; crystalline D-glucaric acid are presented.

Research results based upon these data are published at http://doi.org/10.1002/ejoc.201701343


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Last updated on 2019-23-07 at 11:03