Teitl: Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry

Dyfyniad
Polidano K, Reed-Berendt BG, Basset A, et al. (2017). Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry. Cardiff University. http://doi.org/10.17035/d.2017.0044059416


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2017
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 4666
DOI: 10.17035/d.2017.0044059416

Disgrifiad

A hydrogen transfer strategy for the catalytic functionalization of benzylic alcohols via electronic arene activation, accessing a diverse range of bespoke diaryl ethers and aryl amines in excellent isolated yields (38 examples, 70% average yield) has been explored. Taking advantage of the hydrogen transfer approach, the oxidation level of the functionalized products can be selected by judicious choice of simple and inexpensive additives.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High Resolution Mass Spectrometry spectra

Research results based upon these data are published at http://dx.doi.org/10.1021/acs.orglett.7b03441


Prosiectau Cysylltiedig
Homogeneous hydrogen transfer catalysis (01.10.2016 - 30.09.2019)
Homogeneous hydrogen transfer catalysis (01.10.2016 - 30.09.2019)

Diweddarwyd y tro diwethaf ar 2019-23-07 am 11:01