Title: Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry

Polidano K, Reed-Berendt BG, Basset A, et al. (2017). Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry. Cardiff University. http://doi.org/10.17035/d.2017.0044059416

Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2017
Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Software Required: An appropriate NMR processing software is required for raw NMR data files
Estimated total storage size of dataset: Less than 1 gigabyte
Number of Files In Dataset: 4666
DOI: 10.17035/d.2017.0044059416


A hydrogen transfer strategy for the catalytic functionalization of benzylic alcohols via electronic arene activation, accessing a diverse range of bespoke diaryl ethers and aryl amines in excellent isolated yields (38 examples, 70% average yield) has been explored. Taking advantage of the hydrogen transfer approach, the oxidation level of the functionalized products can be selected by judicious choice of simple and inexpensive additives.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High Resolution Mass Spectrometry spectra

Research results based upon these data are published at http://dx.doi.org/10.1021/acs.orglett.7b03441

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Last updated on 2019-23-07 at 11:01