Teitl: Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling


Dyfyniad
Browne DL, Cao Q, Howard JL (2018). Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling. Cardiff University. https://doi.org/10.17035/d.2018.0052918729



Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli

Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk


Crewyr y Set Ddata o Brifysgol Caerdydd


Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2018

Fformat y data: .jpg .fid

Meddalwedd ofynnol: NMR processing software such as Topspin and Mestranova

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit

Nifer y ffeiliau yn y set ddata: 1000

DOI : 10.17035/d.2018.0052918729

DOI URL: http://doi.org/10.17035/d.2018.0052918729

Related URL: http://www.thebrowneresearchgroup.co.uk


Disgrifiad

A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross-coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both Csp3-Csp2andCsp2-Csp2couplings and is tolerant to many important functional groups. The method may offer broad reaching opportunities for the in situ generation and use of organometallic compounds from base metals and their subsequent engagement in synthetic reactions via mechanochemical methods.

The data here contains a selection of 1H, 13C, 19F NMR data, as well as IR, MS and any relevant chromatography information. Some files may be processed in advance and deposited and some may require access to typical processing tools for data of this type.

Research results based upon these data are published at http://doi.org/10.1002/anie.201806480


Allweddeiriau

Mechanochemistry

Prosiectau Cysylltiedig

Diweddarwyd y tro diwethaf ar 2022-29-04 am 14:42