Teitl: Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling

Dyfyniad
Browne DL, Cao Q, Howard JL (2018). Mechanochemical Activation of Zinc and Application to Negishi Cross-Coupling. Cardiff University. http://doi.org/10.17035/d.2018.0052918729


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Crewyr y Set Ddata o Brifysgol Caerdydd

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2018
Fformat y data: .jpg .fid
Meddalwedd ofynnol: NMR processing software such as Topspin and Mestranova
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 1000
DOI: 10.17035/d.2018.0052918729

Disgrifiad

A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross-coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both Csp3-Csp2andCsp2-Csp2couplings and is tolerant to many important functional groups. The method may offer broad reaching opportunities for the in situ generation and use of organometallic compounds from base metals and their subsequent engagement in synthetic reactions via mechanochemical methods.

The data here contains a selection of 1H, 13C, 19F NMR data, as well as IR, MS and any relevant chromatography information. Some files may be processed in advance and deposited and some may require access to typical processing tools for data of this type.

Research results based upon these data are published at http://doi.org/10.1002/anie.201806480



Allweddeiriau

Mechanochemistry

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Diweddarwyd y tro diwethaf ar 2018-28-08 am 15:16

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