Teitl: Synthesis and Reactivity of N-Allenyl Cyanamides

Dyfyniad
Ayres JN, Williams MTJ, Tizzard GJ, et al. (2018). Synthesis and Reactivity of N-Allenyl Cyanamides. Cardiff University. http://doi.org/10.17035/d.2018.0055747356


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Crewyr y Set Ddata o Brifysgol Caerdydd

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2018
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 3056
DOI: 10.17035/d.2018.0055747356

Disgrifiad

N-Allenyl cyanamides have been accessed via a one-pot deoxycyanamidation-isomerization approach using propargyl alcohol and N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS). The utility of this novel class of allenamide was explored through derivatization, with hydroarylation, hydroamination and cycloaddition protocols employed to access an array of cyanamide products that would be challenging to access using existing methods.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

X-ray crystallographic data

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.8b02225


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Diweddarwyd y tro diwethaf ar 2018-17-09 am 13:10