Title: Synthesis and Reactivity of N-Allenyl Cyanamides

Ayres JN, Williams MTJ, Tizzard GJ, et al. (2018). Synthesis and Reactivity of N-Allenyl Cyanamides. Cardiff University. http://doi.org/10.17035/d.2018.0055747356

Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Cardiff University Dataset Creators

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2018
Data format: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Software Required: An appropriate NMR processing software is required for raw NMR data files
Estimated total storage size of dataset: Less than 1 gigabyte
Number of Files In Dataset: 3056
DOI: 10.17035/d.2018.0055747356


N-Allenyl cyanamides have been accessed via a one-pot deoxycyanamidation-isomerization approach using propargyl alcohol and N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS). The utility of this novel class of allenamide was explored through derivatization, with hydroarylation, hydroamination and cycloaddition protocols employed to access an array of cyanamide products that would be challenging to access using existing methods.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High-Resolution Mass Spectrography spectra.

X-ray crystallographic data

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.8b02225

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Last updated on 2018-17-09 at 13:10