Teitl: Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation


Dyfyniad
Melen RL, Carden JL, Wass DF, et al. (2019). Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation. Cardiff University. https://doi.org/10.17035/d.2019.0069666551



Hawliau Mynediad: Creative Commons Attribution 4.0 International

Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk


Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019

Dyddiad dechrau creu'r data: 01.10.2017

Dyddiad gorffen creu'r data: 22.02.2019

Fformat y data: .pdf

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit

Nifer y ffeiliau yn y set ddata: 1

DOI : 10.17035/d.2019.0069666551

DOI URL: http://doi.org/10.17035/d.2019.0069666551

Related URL: https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C8CC09459D#!divAbstract


Disgrifiad

The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields. The experimental and NMR data are provided.


Research
results based upon these data are published at http://doi.org/10.1039/c8cc09459d


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Diweddarwyd y tro diwethaf ar 2022-12-05 am 09:13