Teitl: Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation

Dyfyniad
Melen RL, Carden JL, Wass D, et al. (2019). Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation. Cardiff University. http://doi.org/10.17035/d.2019.0069666551


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Dyddiad dechrau creu'r data: 01.10.2017
Dyddiad gorffen creu'r data: 22.02.2019
Fformat y data: .pdf
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit
Nifer y ffeiliau yn y set ddata: 1
DOI: 10.17035/d.2019.0069666551

Disgrifiad


The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields. The experimental and NMR data are provided.



Research
results based upon these data are published at http://doi.org/10.1039/c8cc09459d


Allweddeiriau

Lewis acids, Reduction

Meysydd Ymchwil

Prosiectau Cysylltiedig

Diweddarwyd y tro diwethaf ar 2019-10-07 am 14:19