Teitl: Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation
Dyfyniad
Melen RL, Carden JL, Wass DF, et al. (2019). Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation. Cardiff University. https://doi.org/10.17035/d.2019.0069666551
Hawliau Mynediad: Creative Commons Attribution 4.0 International
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk
Crewyr y Set Ddata o Brifysgol Caerdydd
Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Dyddiad dechrau creu'r data: 01.10.2017
Dyddiad gorffen creu'r data: 22.02.2019
Fformat y data: .pdf
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit
Nifer y ffeiliau yn y set ddata: 1
DOI : 10.17035/d.2019.0069666551
DOI URL: http://doi.org/10.17035/d.2019.0069666551
Related URL: https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C8CC09459D#!divAbstract
The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields. The experimental and NMR data are provided.
Disgrifiad
Research
results based upon these data are published at http://doi.org/10.1039/c8cc09459d
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