Title: Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation


Citation
Melen RL, Carden JL, Wass D, et al. (2019). Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation. Cardiff University. http://doi.org/10.17035/d.2019.0069666551



Access Rights: Data can be made freely available subject to attribution

Access Method: Click to email a request for this data to opendata@cardiff.ac.uk


Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2019

Coverage start date: 01/10/2017

Coverage end date: 22/02/2019

Data format: .pdf

Estimated total storage size of dataset: Less than 100 megabytes

Number of Files In Dataset: 1

DOI : 10.17035/d.2019.0069666551

DOI URL: http://doi.org/10.17035/d.2019.0069666551

Related URL: https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C8CC09459D#!divAbstract


Description

The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields. The experimental and NMR data are provided.


Research
results based upon these data are published at http://doi.org/10.1039/c8cc09459d


Keywords

Lewis acids, Reduction

Research Areas

Related Projects

Last updated on 2019-19-12 at 12:13