Title: Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation
Citation
Melen RL, Carden JL, Wass DF, et al. (2019). Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation. Cardiff University. https://doi.org/10.17035/d.2019.0069666551
Access Rights: Creative Commons Attribution 4.0 International
Access Method: https://doi.org/10.17035/d.2019.0069666551 will take you to the repository page for this dataset, where you will be able to download the data or find further access information, as appropriate.
Cardiff University Dataset Creators
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2019
Coverage start date: 01/10/2017
Coverage end date: 22/02/2019
Data format: .pdf
Estimated total storage size of dataset: Less than 100 megabytes
Number of Files In Dataset: 1
DOI : 10.17035/d.2019.0069666551
DOI URL: http://doi.org/10.17035/d.2019.0069666551
Related URL: https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C8CC09459D#!divAbstract
The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine substrates, with alkenes and alkynes not being reduced effectively. The use of microwave irradiation on the other hand has permitted alkenes and alkynes to be hydroborated in good yields. The experimental and NMR data are provided.
Description
Research
results based upon these data are published at http://doi.org/10.1039/c8cc09459d
Keywords
Lewis acids, Reduction
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