Teitl: A Ball-Milling Enabled Reformatsky Reaction

Dyfyniad
Cao Q, Stark RT, Fallis IA, et al. (2019). A Ball-Milling Enabled Reformatsky Reaction. Cardiff University. https://doi.org/10.17035/d.2019.0075438608

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019

Dyddiad dechrau creu'r data: 01.06.2017

Dyddiad gorffen creu'r data: 05.01.2019

Fformat y data: .jpg .fid

Meddalwedd ofynnol: .fid files are processed using standard NMR processing software.

DOI : 10.17035/d.2019.0075438608

DOI URL: http://doi.org/10.17035/d.2019.0075438608

Related URL: https://onlinelibrary.wiley.com/doi/10.1002/cssc.201900886

Disgrifiad

The data here contains a selection of 1H, 13C, 19F NMR data, as well as IR, MS and any relevant chromatography information. Some files may be processed in advance and deposited and some may require access to typical processing tools for data of this type.
Abstract: An operationally simple one‐jar one‐step mechanochemical Reformatsky reaction using in situ generated organozinc intermediates under neat grinding conditions has been developed. Notable features are that this reaction protocol requires no solvent, no inert gases and no pre‐activation of the bulk zinc source. The developed process is demonstrated to have good substrate scope (39‐82% yield), and is effective irrespective of the morphology of the zinc source.

Research results based upone these data are published at http://doi.org/10.1002/cssc.201900886