Teitl: Reactions of Hydrazones and Hydrazides with Lewis Acidic Boranes - data

Dyfyniad
Gazis TA, Dasgupta A, Hill MS, et al. (2019). Reactions of Hydrazones and Hydrazides with Lewis Acidic Boranes - data. Cardiff University. https://doi.org/10.17035/d.2019.0081499826

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019

Dyddiad dechrau creu'r data: 01.07.2018

Dyddiad gorffen creu'r data: 31.05.2019

Fformat y data: .pdf, .jpg

Meddalwedd ofynnol: Mercury, SHELEX, MNova

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit

DOI : 10.17035/d.2019.0081499826

DOI URL: http://doi.org/10.17035/d.2019.0081499826

Disgrifiad

The reaction of (diphenylmethylene)hydrazone or 1,4-bis-hydraQ4 zone-ylidene(phenyl)methyl)benzene with Lewis acidic boranes B(2,4,6-F3C6H2)3 or B(3,4,5-F3C6H2)3 generates the Lewis acid– base adducts. Alternatively, when (9H-fluoren-9-ylidene)hydrazone is employed then several products were isolated including 1,2-di(9H-fluoren-9-ylidene)hydrazone, the 2 : 1 borane adduct of NH2–NH2 and the 1-(diarylboraneyl)-2-(9H-fluoren-9-ylidene) hydrazone in which one ArH group has been eliminated. The benzhydrazide starting material also initially gives an adduct when reacted with Lewis acidic boranes which upon heating eliminates ArH generating a CON2B heterocycle.

Data is provided for the synthesis and characterisation of the compounds generated in this project.

Research results based upon these data are published at http://doi.org/10.1039/C9DT01359H