Title: Reactions of Hydrazones and Hydrazides with Lewis Acidic Boranes - data
Citation
Gazis TA, Dasgupta A, Hill MS, et al. (2019). Reactions of Hydrazones and Hydrazides with Lewis Acidic Boranes - data. Cardiff University. https://doi.org/10.17035/d.2019.0081499826
Access Rights: Data is provided under a Creative Commons Attribution (CC BY 4.0) licence
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2019
Coverage start date: 01/07/2018
Coverage end date: 31/05/2019
Data format: .pdf, .jpg
Software Required: Mercury, SHELEX, MNova
Estimated total storage size of dataset: Less than 100 megabytes
DOI : 10.17035/d.2019.0081499826
DOI URL: http://doi.org/10.17035/d.2019.0081499826
The reaction of (diphenylmethylene)hydrazone or 1,4-bis-hydraQ4 zone-ylidene(phenyl)methyl)benzene with Lewis acidic boranes B(2,4,6-F3C6H2)3 or B(3,4,5-F3C6H2)3 generates the Lewis acid– base adducts. Alternatively, when (9H-fluoren-9-ylidene)hydrazone is employed then several products were isolated including 1,2-di(9H-fluoren-9-ylidene)hydrazone, the 2 : 1 borane adduct of NH2–NH2 and the 1-(diarylboraneyl)-2-(9H-fluoren-9-ylidene) hydrazone in which one ArH group has been eliminated. The benzhydrazide starting material also initially gives an adduct when reacted with Lewis acidic boranes which upon heating eliminates ArH generating a CON2B heterocycle. Data is provided for the synthesis and characterisation of the compounds generated in this project. Research results based upon these data are published at http://doi.org/10.1039/C9DT01359H
Description
Keywords
Mechanism, Structure elucidation
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