Title: Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide: data

Citation
Mitchell C, Terranova U, Alshibane I, et al. (2019). Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide: data. Cardiff University. https://doi.org/10.17035/d.2019.0082439850

Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2019

Coverage start date: 03/01/2017

Coverage end date: 09/08/2019

Data format: .xlsx

Estimated total storage size of dataset: Less than 100 megabytes

Number of Files In Dataset: 1

DOI : 10.17035/d.2019.0082439850

DOI URL: http://doi.org/10.17035/d.2019.0082439850

Description

Development of palladium nanoparticles supported on Mo₂C as an active catalyst for the liquid-phase hydrogenation of CO₂ to formate under mild reaction conditions (100 °C and 2.0 MPa of a 1:1 CO₂:H₂ mixture). A series of Pd/Mo₂C catalysts were synthesised via the modified wet-impregnation (MIm) and sol-immobilization (SIm) techniques and evaluated for CO₂ hydrogenation, in an aqueous 1M NaOH solution.

Data includes Formate production with different bases, turn-over number for different catalysis, Formate production as a function of time, Formate production as a function of NaOH concentration and catalyst stability.

Research results based upon these data are published at http://doi.org/10.1039/c9nj02114k