Title: Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide: data


Citation
Mitchell C, Terranova U, Alshibane I, et al. (2019). Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide: data. Cardiff University. http://doi.org/10.17035/d.2019.0082439850



Access Rights: Data is provided under a Creative Commons Attribution (CC BY 4.0) licence

Access Method: Click to email a request for this data to opendata@cardiff.ac.uk


Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2019

Coverage start date: 03/01/2017

Coverage end date: 09/08/2019

Data format: .xlsx

Estimated total storage size of dataset: Less than 100 megabytes

Number of Files In Dataset: 1

DOI : 10.17035/d.2019.0082439850

DOI URL: http://doi.org/10.17035/d.2019.0082439850


Description

Development of palladium nanoparticles supported on Mo2C as an active catalyst for the liquid-phase hydrogenation of CO2 to formate under mild reaction conditions (100 °C and 2.0 MPa of a 1:1 CO2:H2 mixture). A series of Pd/Mo2C catalysts were synthesised via the modified wet-impregnation (MIm) and sol-immobilization (SIm) techniques and evaluated for CO2 hydrogenation, in an aqueous 1M NaOH solution.

Data includes Formate production with different bases, turn-over number for different catalysis, Formate production as a function of time, Formate production as a function of NaOH concentration and catalyst stability.

Research results based upon these data are published at http://doi.org/10.1039/c9nj02114k


Keywords

CO2 hydrogenation, Pd nanoparticles

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Last updated on 2020-13-01 at 12:16