Teitl: Iron-Catalyzed Borrowing-Hydrogen β‐C(sp3)‐Methylation of Alcohols
Dyfyniad
Polidano K, Morrill LC (2019). Iron-Catalyzed Borrowing-Hydrogen β‐C(sp3)‐Methylation of Alcohols. Cardiff University. https://doi.org/10.17035/d.2019.0082983146
Hawliau Mynediad: Darperir Data dan drwydded Creative Commons Attribution (CC BY 4.0)
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk
Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
Nifer y ffeiliau yn y set ddata: 3271
DOI : 10.17035/d.2019.0082983146
DOI URL: http://doi.org/10.17035/d.2019.0082983146
Related URL: http://blogs.cardiff.ac.uk/themorrillgroup/
Herein we report the iron-catalyzed b-C(sp3)-methylation of primary alcohols using methanol as a C1 building block. This borrowing hydrogen approach employs a well-defined bench stable (cyclopentadienone)iron(0) carbonyl complex as precatalyst (5 mol %) and enables a diverse selection of substituted 2-arylethanols to undergo b-C(sp3)-methylation in good isolated yields (24 examples, 65% average yield). Analysis of reaction products from this methodology resulted in the following data: 1H, 19F and 13C NMR raw data files IR spectra High resolution mass spectrometry spectra. Research results based upon these data are published at http://doi.org/10.1021/acscatal.9b02461.
Disgrifiad
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