Teitl: Manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols via alkoxy radicals: dataset

Dyfyniad
Allen BDW, Mishra D, Seastram AC, et al. (2019). Manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols via alkoxy radicals: dataset. Cardiff University. https://doi.org/10.17035/d.2019.0087324419

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019

Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd

Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit

DOI : 10.17035/d.2019.0087324419

DOI URL: http://doi.org/10.17035/d.2019.0087324419

Related URL: http://blogs.cardiff.ac.uk/themorrillgroup/

Disgrifiad

A manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols has been developed. This electrochemical method provides access to alkoxy radicals from alcohols and exhibits a broad substrate scope, with various cyclopropanols and cyclobutanols converted into synthetically useful β- and γ-chlorinated ketones (40 examples). Furthermore, the combination of recirculating flow electrochemistry and continuous inline purification was employed to access products on a gram scale.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High resolution mass spectrometry spectra

Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.9b03652