Teitl: Manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols via alkoxy radicals: dataset
DyfyniadAllen BDW, Hareram MD, Seastram AC, et al. (2019). Manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols via alkoxy radicals: dataset. Cardiff University. http://doi.org/10.17035/d.2019.0087324419
Hawliau Mynediad: Darperir Data dan drwydded Creative Commons Attribution (CC BY 4.0)
Crewyr y Set Ddata o Brifysgol Caerdydd
Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Fformat y data: .txt, .inmr, .info, .par, .xml, .pdf, .temp, .back, .jpg, .ispd
Meddalwedd ofynnol: An appropriate NMR processing software is required for raw NMR data files
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai nag 1 gigabeit
DOI: 10.17035/d.2019.0087324419
DisgrifiadA manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols has been developed. This electrochemical method provides access to alkoxy radicals from alcohols and exhibits a broad substrate scope, with various cyclopropanols and cyclobutanols converted into synthetically useful β- and γ-chlorinated ketones (40 examples). Furthermore, the combination of recirculating flow electrochemistry and continuous inline purification was employed to access products on a gram scale.
Analysis of reaction products from this methodology resulted in the following data:
1H, 19F and 13C NMR raw data files
IR spectra
High resolution mass spectrometry spectra
Research results based upon these data are published at http://doi.org/10.1021/acs.orglett.9b03652