Teitl: N-Heterocyclic Carbene Acyl Anion Organocatalysis by Ball-Milling

Dyfyniad
Nicholson W I, Seastram AC, Iqbal SA, et al. (2019). N-Heterocyclic Carbene Acyl Anion Organocatalysis by Ball-Milling. Cardiff University. http://doi.org/10.17035/d.2019.0087455694


Hawliau Mynediad: Darperir Data dan drwydded Creative Commons Attribution (CC BY 4.0)
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Dyddiad dechrau creu'r data: 01.06.2017
Dyddiad gorffen creu'r data: 02.09.2019
Fformat y data: .jpg .fid
Meddalwedd ofynnol: .fid files are processed using standard NMR processing software.
DOI: 10.17035/d.2019.0087455694

Disgrifiad

The data here contains a selection of 1H, 13C, 19F NMR data, as well as IR, MS and any relevant chromatography information. Some files may be processed in advance and deposited and some may require access to typical processing tools for data of this type.
Abstract: The ability to conduct N-Heterocyclic carbene catalysed acyl anion chemistry under ball-milling conditions is reported for the first time. This process has been exemplified through applications to intermolecular-benzoin, intramolecular-benzoin, intermolecular- Stetter and intramolecular-Stetter reactions including asymmetric examples and demonstrates that this mode of mechanistically complex organocatalytic reaction can operate under solvent minimised conditions.

Reserach results based upon these data are published at https://doi.org/10.1002/cssc.201902346



Allweddeiriau

Mechanochemistry

Prosiectau Cysylltiedig
Homogeneous hydrogen transfer catalysis (01.10.2016 - 30.09.2019)

Diweddarwyd y tro diwethaf ar 2020-26-06 am 10:58