Teitl: 1,3-Carboboration of iodonium ylides

Dyfyniad
Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al. (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. http://doi.org/10.17035/d.2019.0090828346


Hawliau Mynediad: Gall data fod ar gael yn rhad ac am ddim yn amodol ar briodoli
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2020
Dyddiad dechrau creu'r data: 01.03.2018
Dyddiad gorffen creu'r data: 01.12.2019
Fformat y data: .pdf, .jpeg, .cif
Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit
DOI: 10.17035/d.2019.0090828346

Disgrifiad

Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.

The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data.

Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D



Allweddeiriau

Structure elucidation

Prosiectau Cysylltiedig

Diweddarwyd y tro diwethaf ar 2020-03-03 am 15:08