Title: 1,3-Carboboration of iodonium ylides

Citation
Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al. (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. http://doi.org/10.17035/d.2019.0090828346


Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2020
Coverage start date: 01/03/2018
Coverage end date: 01/12/2019
Data format: .pdf, .jpeg, .cif
Estimated total storage size of dataset: Less than 100 megabytes
DOI: 10.17035/d.2019.0090828346

Description

Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.

The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data.

Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D



Keywords

Structure elucidation

Related Projects

Last updated on 2020-03-03 at 15:08