Title: 1,3-Carboboration of iodonium ylides

Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al. (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. http://doi.org/10.17035/d.2019.0090828346

Access Rights: Data can be made freely available subject to attribution

Access Method: Click to email a request for this data to opendata@cardiff.ac.uk

Dataset Details

Publisher: Cardiff University

Date (year) of data becoming publicly available: 2020

Coverage start date: 01/03/2018

Coverage end date: 01/12/2019

Data format: .pdf, .jpeg, .cif

Estimated total storage size of dataset: Less than 100 megabytes

DOI : 10.17035/d.2019.0090828346

DOI URL: http://doi.org/10.17035/d.2019.0090828346


Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.

The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data.

Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D


Structure elucidation

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Last updated on 2020-03-03 at 15:08