Title: 1,3-Carboboration of iodonium ylides
Citation
Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al. (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. http://doi.org/10.17035/d.2019.0090828346
Access Rights: Data can be made freely available subject to attribution
Access Method: Click to email a request for this data to opendata@cardiff.ac.uk
Cardiff University Dataset Creators
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2020
Coverage start date: 01/03/2018
Coverage end date: 01/12/2019
Data format: .pdf, .jpeg, .cif
Estimated total storage size of dataset: Less than 100 megabytes
DOI : 10.17035/d.2019.0090828346
DOI URL: http://doi.org/10.17035/d.2019.0090828346
Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage. The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data. Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D
Description
Keywords
Structure elucidation
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