Teitl:    1,3-Carboboration of iodonium ylides

Dyfyniad
Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al.  (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. https://doi.org/10.17035/d.2019.0090828346

Manylion y Set Ddata

Cyhoeddwr: Cardiff University

Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2020

Dyddiad dechrau creu'r data: 01.03.2018

Dyddiad gorffen creu'r data: 01.12.2019

Fformat y data: .pdf, .jpeg, .cif

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit

DOI : 10.17035/d.2019.0090828346

DOI URL: http://doi.org/10.17035/d.2019.0090828346

Disgrifiad

Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.

The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data.

Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D