Title: 1,3-Carboboration of iodonium ylides
Citation
Gazis TA, Mohajeri Thaker BAJ, Willcox D, et al. (2020). 1,3-Carboboration of iodonium ylides. Cardiff University. https://doi.org/10.17035/d.2019.0090828346
Access Rights: Creative Commons Attribution 4.0 International
Access Method: https://doi.org/10.17035/d.2019.0090828346 will take you to the repository page for this dataset, where you will be able to download the data or find further access information, as appropriate.
Cardiff University Dataset Creators
Dataset Details
Publisher: Cardiff University
Date (year) of data becoming publicly available: 2020
Coverage start date: 01/03/2018
Coverage end date: 01/12/2019
Data format: .pdf, .jpeg, .cif
Estimated total storage size of dataset: Less than 100 megabytes
DOI : 10.17035/d.2019.0090828346
DOI URL: http://doi.org/10.17035/d.2019.0090828346
Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage. The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data. Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D
Description
Keywords
Structure elucidation
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