Teitl: Radical Reactivity of Frustrated Lewis Pairs with Diaryl Esters - data

Dyfyniad
Soltani Y, Dasgupta A, Gazis TA, et al. (2019). Radical Reactivity of Frustrated Lewis Pairs with Diaryl Esters - data. Cardiff University. http://doi.org/10.17035/d.2020.0091287984


Nid yw'r data hwn ar gael ar hyn o bryd oherwydd: Bwriad i gyhoeddi canlyniadau prosiect
Dull Mynediad: I anfon cais i gael y data hwn, ebostiwch opendata@caerdydd.ac.uk

Manylion y Set Ddata
Cyhoeddwr: Cardiff University
Dyddiad (y flwyddyn) pryd y daeth y data ar gael i'r cyhoedd: 2019
Dyddiad dechrau creu'r data: 01.01.2017
Dyddiad gorffen creu'r data: 22.12.2019
Fformat y data: .pdf, .cif
Meddalwedd ofynnol: MNova
Mercury

Amcangyfrif o gyfanswm maint storio'r set ddata: Llai na 100 megabeit
DOI: 10.17035/d.2020.0091287984

Disgrifiad

Here we report the reaction of diaryl substituted esters with frustrated Lewis pairs. Interestingly this results in divergent pathways, one whereby the diaryl moiety is stabilized by the Lewis basic phosphine or the alternative pathway, wherein a single-electron transfer process occurs generating the [Mes3P]/[C(H)Ar2]· radical ion pair. The latter species undergoes a homocoupling reaction to yield tetraphenylethane derivatives. In the presence of olefins, this reactivity can be harnessed through an sp2-sp3 C–C heterocoupling reaction to generate α,β-substituted olefins. Notably, this work showcases a frustrated Lewis pair approach to metal-free radical C–H bond activation with subsequent C–C bond formation which also displays complementary reactivity to other approaches. Data includes description of experimental procedures, NMR data and X-ray data.

Research results based upon these data can be found at https://doi.org/10.1016/j.xcrp.2020.100016



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Diweddarwyd y tro diwethaf ar 2020-24-02 am 10:27